Thermal Equilibrium vs. Decoupling (“Freeze-Out”)
The rule of thumb here is to compare the interaction rate (
) of the particle we are interested in to the expansion rate of the universe. We’ll examine two extremes:
, and
.
The cross-section for weak interaction goes as
, where
is the Fermi constant,
. Thus, for
(recall that
in the relativistic limit):
Let’s compare this to the Hubble expansion rate of early universe, when
, so curvature is negligible. Therefore:
where
is Newton’s constant and
is the effective degeneracy. In order for
, we need:
We know
, so the temperature requirement for decoupling of the weak interaction is:
In general we can say that particles decouple after the rest mass stops being much more that
. We can compute the threshold temperature for particles based on their rest mass:
Relating Temperature and Time in the Radiation-Dominated Era
Recall that the energy density of relativistic bosons is given by:
We also have shown that in the radiation-dominated era,
, so:
Now since
:
A useful relation is that
.
The First 30 Minutes (in 6 frames)
- "Frame 1:"
,
,
,
. To put things in perspective,
. The major players at this point in time are photons (
), electrons and positrons (
), neutrinos (
), and protons and neutrons (
). For
, we’re assuming baryon asymmetry has occurred, and we should note that they only show up in small numbers.
particles are all ultra-relativistic. Let’s figure out our
:
Note that
was computed as [3 species
2 particle/antiparticle pairs with 1 spin state each
fermion factor]. We ignored
because they were not relativistic. Their reactions are:
The last reaction is negligible because it has timescale
minutes. Remember that we derived the neutron-to-proton ratio:
where
. Thus:
The neutron-to-baryon ratio is:
- "Frame 2:"
,
,
,
drops by a factor of 100. Our major player are the same, so:
- "Frame 3:"
,
,
. Now the weak interaction rate falls below the Hubble time (
). Therefore, neutrinos are decoupling from the thermal bath. Before this decoupling occurred, recall that
were all in thermal equilibrium,
. After decoupling,
are in thermal equilibrium, so
. For the neutrinos, their Fermi-Dirac distribution is “frozen” in place:
- "Frame 4:"
,
,
. Because
, it’s hard to make new
. That is,
is a favored interaction over the reverse, so
start to disappear. As they annihilate, entropy is transferred to photons, so the entropy density
is conserved (see Kolb and Turner, 66).